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Recent Developments in Carbocation and Onium Ion Chemistry

Kenneth Laali

Price: £95.00 (hardback)
ISBN-13: 978-0-8412-7414-3
Publication date: 22 May 2008
544 pages,
Series: ACS Symposium Series number 965
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Description
  • Selling point: Authoritative chapters discussing and summarizing most recent progress in the field from various angles
  • Selling point: The collection serves as a reasonable representation of how the field is progressing and evolving, and should serve as a model for younger researchers working on different/related aspects within the discipline.
The volume is a collection of 22 chapters written by leading experts and active researchers in the field focusing on various aspects of carbocation and onium ion chemistry. These include stable ion NMR studies, solvolytic and kinetic studies, computational work, and synthetic/preparative aspects.

Contents
Foreword
Preface
Chapter 1. Experimental and computational NMR spectroscopic investigation of silyl-substituted carbocations
Chapter 2. Super-Stabilization of -Conjugated Cations by Annelation to Bicyclic Frameworks
Chapter 3. Unusually Stable Vinyl Cations
Chapter 4. Vinyl Iodonium Salts as Precursors to Vinyl Cations
Chapter 5. Generation of Alkylideneallyl Cations from Alkylidenecyclopropanone Acetals Selectivity of Reaction with Nucleophiles
Chapter 6. Conformational Studies of Cyclobutylmethyl Cations
Chapter 7. Persistent Organic Cationic Complexes: Structure and Reactivity
Chapter 8. Activation of Electrophilic Sites by Adjacent Cationic Groups
Chapter 9. Stabilized Carbocations as Redox Active Chromophores Preparation of Electrochromic Materials Using Stabilized Carbocations
Chapter 10. Cation Pool Method and Cation Flow Method
Chapter 11. Fluorenylidene and Indenylidene Dications: Insights about Antiaromaticity
Chapter 12. Generation, Stability, and Reactions of Alkylated Fullerene Cations
Chapter 13. Carbocations on Surfaces
Formation of Bicyclobutonium Cation via Ionization of Cyclopropylcarbinyl Chloride Over NaY Zeolite
Chapter 14. MO Calculations involving m-hydrido cation intermediates relevant to the heptane to toluene dehydrocyclization reaction
Chapter 15. Theoretical Studies on Structure and Dynamics of Carbonium Ions
Chapter 16. Quantum Chemical Studies of Carbocations from Oxidized Metabolites of Aza-Polycyclic Aromatic Hydrocarbons (Aza-PAHs)
Chapter 17. How Does Carbocation Stability Control the Beckmann Rearrangement Reaction?
Chapter 18. Solvent Effects on the Chemistry of Bromonium and -Bromo-carbenium Ions as Reactive Intermediates
Chapter 19. Syntheses of the CFY2+ (Y = Cl, Br) and CX3+ (X = Cl, Br, OTeF5) Cations Employing the Noble-Gas Oxidant, XeOTeF5+Sb(OTeF5)6?
Chapter 20. Organoxenonium Salts
Synthesis by "Xenodeborylation", Reactivities, and NMR Spectroscopic Properties
Chapter 21. Halogen transfer reactions from bis-amino halonium ions to acceptor olefins: mechanism and strategies for chiral halogenation
Chapter 22. Synthesis of Phosphonium Salts by Metal-Catalyzed Addition Reaction

Authors, editors, and contributors


Kenneth Laali


Links to web resources and related information
More in the same subject area:
Organic chemistry
Catalysis
Polymer chemistry

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